As an AI, I don't have real-time data or the ability to predict future events such as sports matches. However, I can provide some general information about the teams.
FC Barcelona and Valencia CF are both professional football clubs in Spain. Barcelona is one of the most successful clubs in the world, while Valencia is also a strong team but has not been as successful recently.
The outcome of a match between these two teams can depend on many factors such as the current form of the teams, injuries, the tactics used by the coaches, and even the weather. Therefore, it's not possible for me to predict the result of a match between these two teams.
However, you can check the latest odds and predictions from sports analysts or betting companies for a better idea about the expected outcome of the match.
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